It's on ESPN and ESPN2. The page I'm linking has the dates/times it is shown.
The episodes I watched last weekend were VERY interesting. One focused on the early developments of the game. How it was essentially a blood bath rugby style sport. Details it evolvement into what we see today.
Lots of interesting stories. Notre Dame. Black integration. Small schools who gained famed. Military Academies. College Football during war and the depression. Early Stadiums. How the average folk followed it before TV. First hero's.
I too am considering ordering it on DVD. 130 dollars is a bit much for me right now so I put it on my list to Santa .
Rites of Autumn Website